Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules
نویسندگان
چکیده
The cyano(triphenylsilyl)phosphanide anion was prepared as a sodium salt from 2-phosphaethynolate. electronic structure of this new cyano(silyl)phosphanide studied via computational methods and its reactivity investigated using various electrophiles Lewis acids, demonstrating P- N-nucleophilicity. ambident is in agreement with computations. silyl group also shows lability therefore the can be considered phosphacyanamide synthon, [PCN]2−, serves building block for transfer PCN moiety.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202108295